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Puerto Williams, Chile dec 2023. Puerto Williamss a city, port and naval base on Navarino Island in Chile, and is also the southernmost populated settlement in the world. It faces the Beagle Channel. It is the capital of the Chilean Antarctic Province, one of four provinces in the Magellan and Chilean Antarctica Region, and administers the communes of Chilean Antarctic Territory and Cabo de Hornos. It has a population of 2,874, including both naval personnel and civilians.